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  姓名：李曉芳

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  職稱：長聘教授/博士生導(dǎo)師

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  電子郵箱：xfli@bit.edu.cn

李曉芳，有機(jī)化學(xué)和高分子化學(xué)研究所所長

十年來，本課題組立足于基礎(chǔ)和應(yīng)用研究，以“新催化劑，新聚合反應(yīng)，新 材料”為宗旨，致力于開發(fā)新型的、高效、高選擇性的稀土/過渡金屬有機(jī)配 合物，并探索其在高分子合成（特別是配位聚合反應(yīng)）和有機(jī)合成（特別是 有機(jī)方法學(xué)）中的催化作用，合成出許多具有潛在工業(yè)應(yīng)用前景的聚烯烴或者難以用以往催化劑制備的新型高分子材料和有機(jī)合成試劑。主持國家自然 科學(xué)基金項目 6 項、承擔(dān)企業(yè)合作項目 1 項；參與國家自然科學(xué)基金項目等1 項。迄今在國內(nèi)外學(xué)術(shù)刊物及會議上發(fā)表學(xué)術(shù)論文 60 余篇，其中 SCI 收錄61 篇，EI 收錄 0 篇，獲授權(quán)專利 9 項。

榮譽獎勵

2013 年國家級青年人才項目

2013 年教育部新世紀(jì)人才稱號獲得者

北京理工大學(xué)杰出中青年教師發(fā)展支持計劃 (2009)

承擔(dān)項目

1. 稀土催化烯烴與極性烯烴配位共聚合反應(yīng)制備功能化聚烯烴；面上項 目，國家自然科學(xué)基金委；66 萬元；起始時間：2020, 01；終止時間： 2023, 12；主持。

2. 稀土金屬催化劑絡(luò)合物的合成及放大研究；中國石油天然氣股份有限公 示石油化工研究院；50 萬元；起始時間：2019, 11；終止時間：2021, 12； 主持。

3. 金屬有機(jī)化合物置換型熒光探針熒光檢測烯烴配位聚合反應(yīng)的催化活

性物種；面上項目，國家自然科學(xué)基金委；63 萬元；起始時間：2018, 01；終止時間：2021, 12；主持。

4. 基于三鍵化學(xué)的高分子合成（主持人：唐本忠院士）：21490570，子課 題：新型基于三鍵的聚合反應(yīng)和方法（負(fù)責(zé)人：唐本忠院士）：21490574； 重大項目，國家自然科學(xué)基金委；150/2000 萬元；起始時間：2015, 01， 終止時間：2019, 12，參與。

5. 高分子合成化學(xué)；國家級青年人才項目，國家自然科學(xué)基金委；100 萬元；起始時間：2014, 01；終止時間：2016, 12；主持。

6. 稀土催化劑合成；新世紀(jì)人才支持計劃，教育部；50 萬元；起始時間：

2014, 01；終止時間：2015, 12；主持。

7. 稀土催化劑通過配位共聚合方法制備高立構(gòu)規(guī)整性 1,3-環(huán)己二烯基共聚 物；面上項目，國家自然科學(xué)基金委；82 萬元；起始時間：2013, 01； 終止時間：2016, 12；主持。

8. 稀土催化劑促進(jìn)烯烴和共軛二烯烴配位共聚合反應(yīng)的研究；面上項目， 國家自然科學(xué)基金委；38 萬元；起始時間：2010, 01；終止時間：2012, 12；主持。

9. 稀土-鋅簇催化二氧化碳和環(huán)氧烷烴共聚合反應(yīng)；人事部留學(xué)人員科技 活動項目擇優(yōu)資助優(yōu)秀項目；4 萬元；起始時間：2011, 01；終止時間： 2012, 12；主持。

10. 非茂陽離子型稀土金屬烯烴聚合催化劑的研究；教育部留學(xué)回國人員啟 動經(jīng)費項目；4 萬元；起始時間：2009, 09；終止時間：2010, 09；主持。

1. 稀土/過渡金屬有機(jī)化學(xué)

2. 高分子合成化學(xué)

3. 烯/炔烴配位聚合反應(yīng)

4. 有機(jī)方法學(xué)

2000.09-2003.12 中國科學(xué)院長春應(yīng)用化學(xué)研究所，有機(jī)化學(xué)專業(yè)，理學(xué)博士

1997.09-2000.07 東北師范大學(xué)，有機(jī)化學(xué)專業(yè)，理學(xué)碩士

1993.09-1997.07 東北師范大學(xué)，化學(xué)教育專業(yè)，理學(xué)學(xué)士

2008.02-至今 北京理工大學(xué)化學(xué)與化工學(xué)院，長聘教授/博士生導(dǎo)師/有機(jī)
所所長

2014.10-2014.12 香港科技大學(xué)化學(xué)與化工學(xué)院唐本忠課題組，訪問學(xué)者

2004.04-2009.04 日本理化學(xué)研究所，有機(jī)金屬實驗室，博士后

十年來，我們立足于基礎(chǔ)和應(yīng)用研究，以“新催化劑，新聚合反應(yīng)，新 材料”為宗旨，致力于開發(fā)新型的、高效、高選擇性的稀土/過渡金屬有機(jī)配 合物，并探索其在高分子合成（特別是配位聚合反應(yīng)）和有機(jī)合成（特別是 有機(jī)方法學(xué)）中的催化作用，合成出許多具有潛在工業(yè)應(yīng)用前景的聚烯烴或者難以用以往催化劑制備的新型高分子材料和有機(jī)合成試劑。主持國家自然 科學(xué)基金項目 6 項、承擔(dān)企業(yè)合作項目 1 項；參與國家自然科學(xué)基金項目等1 項。迄今在國內(nèi)外學(xué)術(shù)刊物及會議上發(fā)表學(xué)術(shù)論文 60 余篇，其中 SCI 收錄61 篇，EI 收錄 0 篇，獲授權(quán)專利 9 項。

代表性論 文（近 五年以 來）

1. H. Liu,a S.-W. Zhang,a X.-Q. Yan,a C. Song,a J.-P. Chen,a Y.-P. Dong*b and X.-F. Li*a. Silylium Cations Initiated Sergeants-and-Soldiers Type Chiral Amplification of Helical Aryl Isocyanide Copolymers. Polymer Chemistry, 2020, 11, 6017-6028.

2. L. Zhang,a Q.-B. Cao,a F. Gao,a Y.-P. Dong*b and X. - F. Li*. Self-Supported Rhodium Catalysts Based on a Microporous Metal-Organic Framework for Polymerization of Phenylacetylene and Its Derivatives. Polymer Chemistry, 2020, 11, 2904-2913.

3. X.-L. Wu, X.-W. Yan, Z. Yang, S.-W. Zhang, Y.-P. Dong*, J.-G. Zhi* and X.- F. Li*. AliBu3: Unprecedented Main-Group Metal Catalyst for Helical-Sense- Selective Polymerization of Chiral Aryl Isocyanides and Copolymerization with Achiral Aryl Isocyanides. Mater. Chem. Front.2019, 3, 1192-1198.

4. X.-L. Wu, P.-F. Zhang, S.-W. Zhang, Z. Yang, W.-J. Chi, G. Guo, H. Liu, Y.-P. Dong*, N.-N. Qiu*, L. Yan and X. - F. Li*. Polymerization of phenylacetylenes by binuclear rhodium catalysts with different para- binucleating phenoxyiminato linkages. Polymer Chemistry, 2019, 10, 4163- 4172.

5. G. Guo, X.-L. Wu, X.-Q. Yan, Y. Li, X. - F. Li*, S.-W. Zhang* and N.-N. Qiu*. Unprecedentedly High Activity and/or High Regio-/Stereoselectivity of Fluorenyl-Based CGC Allyl-Type η3: η1-tert-Butyl (dimethylfluorenylsilyl) amido Ligated Rare Earth Metal Monoalkyl Complexes in Olefin Polymerization. Polymers, 2019, 5, 836.

6. X.-W. Yan, S.-W. Zhang, P.-F. Zhang, X.-L. Wu, A. Liu, G. Guo, Y.-P. Dong* and X.- F. Li*.[Ph3C][B(C6F5)4]: A Highly Efficient Metal‐Free Single‐ Component Initiator for the Helical ‐ Sense ‐ Selective CationicCopolymerization of Chiral Aryl Isocyanides and Achiral Aryl Isocyanides.Angewandte Chemie International Edition, 2018, 57, 8947–8952.

7. X.-L. Wu, Z. Yang, X.-W. Yan, P.-F. Zhang, L. Wang, G. Guo, Y.-P. Dong and X. - F. Li *. Polymerization of 1-Chloro-2-Phenylacetylenes by Cationic Monoanionic Tridentate (S,S)-Bis(oxazolinylphenyl)amido-Ligated Palladium Catalysts: Is It Coordination-Insertion Mechanism? Polymer Chemistry, 2018, 9, 4856-4865.

8. F. Gao L. Zhang C. Yu X.-W. Yan S.-W. Zhang X. - F. Li *. Controlled Polymerization of Isoprene with Chromium ‐ Based Metal ‐ Organic Framework Catalysts: Switching from Cyclic to cis ‐ 1,4 ‐ Selectivity Depending on Activator. Macromolecular Rapid Communications, 2018, 39, 1800002

9. D.-Q. Peng, X.-W. Yan, S.-W. Zhang*, X. - F. Li *. Syndiotactic Polymerization of Styrene and Copolymerization with Ethylene Catalyzed by Chiral Half-sandwich Rare-earth Metal Dialkyl Complexes. Chinese Journal of Polymer Science, 2018, 36, 222?230.

10. C. Yu, P.-F. Zhang, F. Gao, S.-W. Zhang* and X.- F. Li*. A Displacement-type Fluorescent Probe Reveals Active Species in the Coordinative Polymerization of Olefins. Polymer Chemistry, 2018, 9, 603–610.

11. X.-W. Yan, S.-W. Zhang, D.-Q. Peng, P.-F. Zhang, J.-G. Zhi, X.-L.Wu, L. Wang, Y.-P. Dong * and X. -F. Li *. Cationic Half-sandwich Rare-earth Metal Alkyl Species Catalyzed Polymerization Copolymerization of Aryl Isocyanides Possessing Polar, Bulky, or Chiral Substituents. Polymer Chemistry, 2018, 9, 984–993.

12. X.-Q. Yan, F.-Z. Yang*, G.-L. Cai, Q.-W. Meng, and X. - F. Li*. Nickel(0)- Catalyzed Inert C-O Bond Functionalization: Organo Rare-Earth Metal Complex as the Coupling Partner. Organic Letters, 2018, 20, 624?627.

13. P.-F. Zhang, H.-Y. Liao, H.-H. Wang, X.- F. Li *. F.-Z. Yang*, and S.-W. Zhang*. Cis-1,4-Polymerization of Isoprene Catalyzed by 1,3-Bis(2- pyridylimino)isoindoline-Ligated Rare-Earth-Metal Dialkyl Complexes .Organometallics, 2017, 36, 2446–2451.

14. C. Yu, D.-H. Zhou, X.-Q. Yan, F. Gao, L. Zhang, S.-W. Zhang* and X. - F. Li *. Cis-1,4-Polymerization of Isoprene by 1,3- Bis(oxazolinymethylidene)isoindoline-Ligated Rare-Earth Metal Dialkyl Complexes. Polymers, 2017, 9, 531-542.

15. F.-Z. Yang, X. - F. Li *. Novel Cationic Rare Earth Metal Alkyl Catalysts for Precise Olefin Polymerization. Journal of Polymer Science, Part A: Polymer Chemistry. 2017, 55, 2271–2280.

16. Y. Tian, X. - F. Li *, J.-B. Shi, B. Tong, Y.-P. Dong*. Monomer-induced Switching of Stereoselectivity and Limitation of Chain Growth in the Polymerization of Amine-containing Para-substituted Phenylacetylenes by [Rh(norbornadiene)Cl]2. Polymer Chemistry, 2017, 8, 5761-5768.

17. Y.-D. Huang, J.-Y He, Z.-X. Liu, P.-F. Zhang, G.-L. Cai, S.-W. Zhang, and X. - F. Li *. A Highly Active Chiral (S, S)-Bis(oxazoline) Pd(II) Alkyl Complex/Activator Catalytic System for Vinyl Polymerization of Norbornene in Air and Water. Polymer Chemistry, 2017, 8, 1217-1222.

18. Y.-D. Huang, J.-Y. He, G.-L. Cai, Z.-X. Liu, T.-T. Li, T.-T. Du, S.-W. Zhang, B. Yao, and X. - F. Li *. cis-1,4-Specific Carbocationic Polymerization and Copolymerization of 1,3-Dienes Initiated by (S,S)- Bis(oxazolinylphenyl)amine Chromium Complexes. Journal of Polymer Science, Part A: Polymer Chemistry, 2017, 55, 1250–1259.

19. G.-X. Du, X.-W. Yan, P.-F. Zhang, H.-H. Wang, Y.-P. Dong, X.- F. Li*. 1,4-Specific Copolymerization of 1,3-Cyclohexadiene with Isoprene and Their Terpolymerization with Styrene by Cationic Half-Sandwich Fluorenyl Rare Earth Metal Alkyl Catalysts, Polymer Chemistry, 2017, 8, 698-707.

20. P.-F. Zhang, H.-H. Wang, X.-S. Shi, X.-W. Yan, X.-L. Wu, S.-W. Zhang, B. Yao, X. Feng, J.-G. Zhi, X.- F. Li* , B. Tong, J.-B. Shi, L. Wang, Y.-P. Dong*. On-Water Polymerization of Phenylacetylene Catalyzed by Rh Complexes Bearing Strong π-Acidic Dibenzo[a,e]cyclooctatetraene Ligand. Journal of Polymer Science, Part A: Polymer Chemistry, 2017, 55, 716–725, Special Issue for Prof. Ben Zhong Tang.

21. G.-L. Cai, Y.-D. Huang, T.-T. Du, S.-W. Zhang, B. Yao*, X.- F. Li*, Palladium-Catalyzed C(sp3)–C(sp2) Cross-Coupling of Homoleptic Rare- Earth Metal Trialkyl Complexes with Aryl Bromides: Efficient Synthesis of Functionalized Benzyltrimethylsilanes, Chemical Communications, 2016, 52, 5425?5427.

22. G.-l. Cai, Z.-B. Zhou, W.-C. Wu, B. Yao,* S.-W. Zhang, X. - F. Li*. Pd- Catalyzed C(sp3)–C(sp2) Cross-Coupling of Y(CH2SiMe3)3(THF)2 with Vinyl Bromides and Triflates, Organic & Biomolecular Chemistry, 2016, 14, 8702– 8706.

23. D.-Q. Peng, X.-W. Yan, C. Yu, S.-W. Zhang, X.- F. Li* . Transition Metal Complexes Bearing Tridentate Ligands for Precise Olefin Polymerization, Polymer Chemistry, 2016, 7, 2601–2634.

24. D.-Q. Peng, G.-X. Du, P.-F. Zhang, B. Yao, X.- F. Li*, S.-W. Zhang*. Regio- and Stereochemical Control in Ocimene Polymerization by Half-Sandwich Rare-Earth Metal Dialkyl Complexes, Macromolecular Rapid Communications, 2016, 37, 987?992.

25. G.-X. Du, Y.-Y. Long, J.-P. Xue, S.-W. Zhang, Y.-P. Dong, X. - F. Li*. 1,4-Selective Polymerization of 1,3-Cyclohexadiene and Copolymerization with Styrene by Cationic Half-Sandwich Fluorenyl Rare Earth Metal Alkyl Catalysts, Macromolecules, 2015, 48, 1627?1635.

26. G.-X. Du, J.-P. Xue, D.-Q. Peng, C. Yu, H.-H. Wang, Y.-N. Zhou, J.-J. Bi, S.-W. Zhang, Y.-P. Dong, X. - F. Li*. Copolymerization of Isoprene with Ethylene Catalyzed by Cationic Half-Sandwich Fluorenyl Scandium Catalysts, Journal of Polymer Science, Part A: Polymer chemistry, 2015, 53, 2898–2907.

27. S.-Q. Liu, G.-X. Du, J.-Y. He, Y.-Y. Long, S.-W. Zhang*, X.- F. Li*. Cationic Tropidinyl Scandium Catalyst: A Perfectly Acceptable Substitute for Cationic Half-Sandwich Scandium Catalysts in cis-1,4-Polymerization of Isoprene and Copolymerization with Norbornene, Macromolecules, 2014, 47, 3567?3573.

28. H. Liu, J.-Y. He, Z.-X. Liu, Z.-G. Lin, G.-X. Du, S.-W. Zhang,* and X.- F. Li *. Quasi-Living trans-1,4-Polymerization of Isoprene by Cationic Rare Earth Metal Alkyl Species Bearing a Chiral (S,S)- Bis(oxazolinylphenyl)amido Ligand, Macromolecules 2013, 46, 3257?3265.

以第一作 者發(fā)表 的 代表 性 論文 (2004-2010)

1. X. - F. Li , Z.-M. Hou*. Scandium-Catalyzed Regio- and Stereospecific cis- 1,4-Polymerization of 1,3-Cyclohexadiene and Copolymerization with Ethylene, Macromolecules, 2010, 43, 8904?8909.

2. X. - F. Li, M. Nishiura, L.-H. Hu, K. Mori, Z.-M. Hou*. Alternating and Random Copolymerization of Isoprene and Ethylene Catalyzed by Cationic Half-Sandwich Scandium Alkyls, Journal of the American Chemical Society, 2009, 131, 13870?13882.

3. X. - F. Li , Z.-M. Hou*. Organometallic Catalysts for Copolymerization of Cyclic Olefins, Coordination Chemistry Reviews, 2008, 252, 1842?1869.

4. X. - F. Li, M. Nishiura, K. Mori, T. Mashiko, Z.-M. Hou*. Cationic Scandium Aminobenzyl Complexes. Synthesis, Structure and Unprecedented Catalysis of Copolymerization of 1-Hexene and Dicyclopentadiene, Chemical Communications, 2007, 40, 4137?4139.

5. X. - F. Li, J. Baldannis, M. Nishiura, O. Tardif, Z.-M. Hou*. Cationic Rare- Earth Polyhydrido Complexes: Synthesis, Structure, and Catalytic Activity for the cis-1,4-Selective Polymerization of 1,3-Cyclohexadiene, Angewandte Chemie International Edition, 2006, 45：8184?8188.

6. X. - F. Li , J. Baldamus, Z.-M. Hou*. Alternating Ethylene-Norbornene Copolymerization Catalyzed by Cationic Half-Sandwich Scandium Complexes, Angewandte Chemie International Edition, 2005, 44, 962?965.

7. X. - F. Li , Z.-M. Hou*. Scandium-Catalyzed Copolymerization of Ethylene with Dicyclopentadiene and Terpolymerization of Ethylene, Dicyclopentadiene, and Styrene, Macromolecules, 2005, 38, 6767?6769.

8. X. - F. Li, K. Dai, W.-P. Ye, L. Pan, Y.-S. Li*. New Titanium Complexes with Two Beta-Enaminoketonato Chelate Ligands: Syntheses, Structures, and Olefin Polymerization Activities, Organometallics, 2004, 23, 1223?1230.