個(gè)人簡(jiǎn)介
1987 年本科畢業(yè)于東北師范大學(xué)化學(xué)系,1990 年中科院長(zhǎng)春應(yīng)用化學(xué)研究所碩士研究生,1995 年12 月莫斯科大學(xué)化學(xué)系弗魯姆金電化學(xué)教研室獲得副博士學(xué)位,1997 年 12 月北京大學(xué)化學(xué)學(xué)院博士后出站后到首都師范大學(xué)化學(xué)系工作,2000 年評(píng)定研究員職稱(chēng),2006 年初到北京理工大學(xué)理學(xué)院化學(xué)系任教。
作為項(xiàng)目負(fù)責(zé)人承擔(dān)了國(guó)家、北京市自然科學(xué)基金,教育部的“優(yōu)秀青年教師計(jì)劃”和“高等學(xué)校骨干教師資助計(jì)劃”,北京市“科技新星”培養(yǎng)計(jì)劃等 10 項(xiàng)。目前承擔(dān)國(guó)家自然科學(xué)基金面上項(xiàng)目:掃描電化學(xué)顯微鏡方法研究自組裝膜表面氫鍵協(xié)同作用,資助期限 2019.01-2022.12,直接經(jīng)費(fèi) 65 萬(wàn)。近 10 年已培養(yǎng)碩士 24 名,博士 12 名。目前在讀碩士生 4 名、博士生 2 名。在電極表面的分子自組裝膜構(gòu)筑、表征及氫鍵電化學(xué)等電化學(xué)研究方面已發(fā)表 SCI 收錄論文 61 篇。
研究領(lǐng)域和方向
自組裝單分子膜電化學(xué)。從新研究方法的建立,研究體系選擇與優(yōu)化及研究?jī)?nèi)容提煉與深入等方面對(duì)自組裝膜體系分子間弱相互作用進(jìn)行研究。具體為運(yùn)用掃描電化學(xué)顯微鏡方法(SECM)研究氫鍵、電化學(xué)調(diào)控氫鍵、π-π 相互作用、靜電作用及離子對(duì)效應(yīng)等對(duì)氫鍵行為影響的研究,并應(yīng)用于電化學(xué)傳感器的研究。
教育背景
1991-1995 莫斯科大學(xué)化學(xué)系,弗魯姆金電化學(xué)教研室,副博士
1990-1991 中科院長(zhǎng)春應(yīng)用化學(xué)研究所 碩士
1983-1987 東北師范大學(xué) 化學(xué)系 學(xué)士
工作履歷
2006-至今 北京理工大學(xué),化學(xué)與化工學(xué)院,教授
2000-2006 首都師范大學(xué),化學(xué)系,研究員
1998-2000 首都師范大學(xué),化學(xué)系,副教授
1996-1997 北京大學(xué),化學(xué)與分子工程學(xué)院,博士后
1987-1990 東北林業(yè)大學(xué),化學(xué)系,助教
研究成果
近些年本組研究生為第一作者發(fā)表論文如下:
1、N. Li, X. M. Huang, J. C. Chen, H. B. Shao*.
Investigating the conversion from coordination bond to electrostatic interaction on self-assembled monolayer by SECM.
Electrochimica Acta, 2022, 423, 140569 - 140572.
2、A. H Fan, J. C. Chen, N. Li, H. X Guo, X. Li, L. L. Zhang, H. B. Shao*.
Probing Ca2+-induced electron transfer on the surface of self-assembled monolayer using SECM.
J. Electroanal. Chem., 2022, 914, 116292 – 116300.
3、L. L. Zhang, N. Li, Z. Z. Chen, X. Li, A. H Fan, H. B. Shao*.
Investigating the substitution of intermolecular hydrogen bonds on the surface of self-assembled monolayer by scanning electrochemical microscopy.
J. Electroanal. Chem., 2022, 923, 116790 - 116795.
4、X. Li, N. Li, Z. Z. Chen, H. B. Shao*.
Study of the electrostatic repulsion of the carboxylic surface in the diffusion layer by scanning electrochemical microscopy.
J. Chin. Chem. Soc., 2022, 69, 1088 – 1095.
5、N. Li, J. C. Chen, X. M. Huang, H. X. Guo, X. Li, A. H. Fan, H. B. Shao*.
Competition of ion-pair during the transition from hydrogen bonding to electrostatic interaction on self-assembled monolayer.
Electrochimica Acta, 2021, 397, 139310 - 139321.
6、J. C. Chen, X. M. Huang, N. Li, H. X. Guo, Z. M. Gao, H. B. Shao*.
Quantitative analysis of the hydrogen bond Interaction between tyrosine and a simulated cell membrane by SECM.
J. Phys. Chem. C, 2021, 125, 410 - 418
7、X. M. Huang, J. C. Chen, C. X. Yan, H. X. Guo, H. B. Shao*.
Probing Charge Reversal of Zwitterion at Defects on Self-Assembled Monolayers by Scanning Electrochemical Microscopy.
J. Phys. Chem. C, 2020, 124, 8876 - 8884.
8、J. C. Chen, X. M. Huang, C. X. Yan, H. X. Guo, Z. M. Gao, H. B. Shao*.
Controllable release of dopamine from simulated enzyme-containing biomembrane by biased potential.
Analytica Chimica Acta, 2020, 1125, 135 - 143.
9、J. C. Chen, X. M. Huang, X. T. Fang, C. X. Yan, Z. M. Gao, H. B. Shao*.
Disassembly of intermolecular hydrogen bond induced by cations on selfassembled monolayer.
J. Electroanal. Chem., 2020, 876, 114476
10、X. M. Huang, J. C. Chen, C. X. Yan, H. B. Shao*.
Probing a Reversible Cationic Switch on a Mixed Self-Assembled Monolayer Using Scanning Electrochemical Microscopy.
Langmuir, 2019, 35, 10772 - 10779.
11、Q. Zheng, H. B. Shao*.
Correlation between redox species adsorption and electron transfer kinetics of mildly oxidized graphene: A chronocoulometry and SECM study.
Electrochemistry Communications, 2019,103, 83 - 87.
12、X. M. Huang, J. C. Chen, X. T. Fang, C. X. Yan, H. B. Shao*.
Exploring the enhancement of electron tunneling induced by intermolecular interactions on surface of self-assembled monolayer.
J. Electroanal. Chem., 2019, 837, 143 - 150.
13、C. X. Yan, X. M. Huang, J. C. Chen, H. X. Guo, H. B. Shao*.
Study on Preferential Solvation of Water by Electrochemical Method.
Electroanalysis, 2019, 31, 1 - 9.
14、X. M. Huang, Q. Zheng, X. T. Fang, H. B. Shao*.
Probing Qualitative Change in Intermolecular Forces from Hydrogen Bonding to Electrostatic Interaction on the Surface of Self-Assembled Monolayer.
Journal of The Electrochemical Society, 2018, 165 (5), H240 - H246.
15、Q. Zheng, H. B. Shao*. Influence of intermolecular H-bonding on the acid-base interfacial properties of -COOH and ferrocene terminated SAM.
J. Electroanal. Chem., 2018, 829, 88 - 94.