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  姓名：楊曉娟

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  職稱：教授/博士生導師

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  電子郵箱：yangxj@bit.edu.cn

課題組長期開展金屬有機化學方向的研究工作，在金屬-金屬鍵化合物的構(gòu)建和反應(yīng)性、金屬誘導的小分子活化、以及金屬有機超分子組裝等方面取得了良好的成績。主持和參與多項國家自然科學基金及其它項目。已發(fā)表SCI論文150余篇，獲陜西省科學技術(shù)獎、中科院“百人計劃”、“盧嘉錫優(yōu)秀導師獎”等榮譽。

1. 金屬-金屬鍵及低價態(tài)金屬配合物的合成

2. 金屬誘導的小分子活化

3. 超分子金屬有機化學

1995.09-1998.06 福州大學，功能材料研究所，物理化學專業(yè)，理學博士

1992.09-1995.06 蘭州大學，無機化學專業(yè)，理學碩士

1988.09-1992.06 蘭州大學，無機化學專業(yè)，理學學士

2020.11-至今 北京理工大學化學與化工學院，教授/博導

2013.04-2020.10 西北大學化學與材料科學學院，教授/博導

2005.09-2013.04 中科院蘭州化學物理研究所，研究員/博導

1999.05-2005.09 美國佐治亞、瑞士日內(nèi)瓦、德國弗萊堡大學化學系，博士后

1. L. Liang, W. Zhao,* X.-J. Yang, B. Wu,* Anion-Coordination-Driven Assembly. Acc. Chem. Res. 2022, 55, 3218?3229.

2. V. A. Dodonov, V. G. Sokolov, E. V. Baranov, A. A. Skatova, W. Xu, Y. Zhao, X.-J. Yang,* I. L. Fedushkin*, Reactivity of Transition Metal Gallylene Complexes Toward Substrates with Multiple Carbon?Element Bonds. Inorg. Chem. 2022, 61, 14962?14972.

3. Y. Xue, J. Wang, Y. Shi, W. Xu, Y. Zhao, B. Wu, X.-J. Yang,* Assembly of metallo- macrocycles through reductive C–C coupling of alkylnitriles by an Mg–Mg-bonded compound. Dalton Trans. 2022, 51, 4394–4399.

4. R. Zhang, Y. Wang, Y. Zhao, C. Redshaw, I. L. Fedushkin, B. Wu, X.-J. Yang*, Main-group metal complexes of α-diimine ligands: structure, bonding and reactivity. Dalton Trans., 2021, 50, 13634-13650.

5. V. A. Dodonov, W. Chen, L. Liu, V. G. Sokolov, E. V. Baranov, A. A. Skatova, Y. Zhao,* B. Wu, X.-J. Yang,* I. L. Fedushkin,* Reactions of Iso(thio)cyanates with Dialanes: Cycloaddition, Reductive Coupling, or Cleavage of the C=S or C=O Bond. Inorg. Chem. 2021, 60, 14602?14612.

6. W. Chen, V. A. Dodonov, V. G. Sokolov, L. Liu, E. V. Baranov, Y. Zhao,* I. L. Fedushkin,* X.-J. Yang,* Activation of Nitrogen-Rich Substrates by Low-Valent, Redox-Active Aluminum Species. Organometallics 2021, 40(4), 490–499.

7. W. Chen, L. Liu, Y. Zhao*, Y. Xue, N. Li, B. Wu, X.-J. Yang,* Organometallo-macrocycle assembled through dialumane-mediated C?H activation of pyridines. Chem. Commun. 2021, 57, 6268–6271.

8. L. Shen, Y. Zhao, D. Dai, Y.-W. Yang*, B. Wu, X.-J. Yang,* Stabilization of Grignard reagents by a pillar[5]arene host – Schlenk equilibria and Grignard reactions. Chem. Commun., 2020, 56, 1381?1384.

9. M. Ma, L. Shen, H. Wang, Y. Zhao, B. Wu, X.-J. Yang*, N,N′?Dipp?o? phenylene-diamido Dianion: A Versatile Ligand for Main Group Metal?Metal-Bonded Compounds. Organometallics 2020, 39, 1440?1447.

10. V. A. Dodonov, L. Xiao, O. A. Kushnerova, E. V. Baranov, Y. Zhao*, X.-J. Yang*, I. L. Fedushkin*, Transformation of carbodiimides to guanidine derivatives facilitated by gallylenes. Chem. Commun. 2020, 56, 7475?7478.

11. L. Xiao, W. Chen, L. Shen, L. Liu, Y. Xue, Y. Zhao*, X.-J. Yang, Reduction of carbodiimides by a dialumane through insertion and cycloaddition. Chem. Commun. 2020, 56, 6352?6355.

12. W. Zuo, C. Jia, H. Zhang, Y. Zhao, X.-J. Yang*, B. Wu*, Selective recognition of choline phosphate by tripodal hexa-urea receptors with dual binding sites: crystal and solution evidence. Chem. Sci., 2019, 10, 2483–2488.

13. M. Ma, H. Wang, J. Wang, L. Shen, Y. Zhao, W.-H. Xu, B. Wu, X.-J. Yang*, Mg–Mg-bonded compounds with N,N’-dipp-substituted phenanthrene-diamido and o-phenylene-diamino ligands. Dalton Trans., 2019, 48, 2295–2299.

14. L. Shen, Y. Zhao, Q. Luo, Q.-S. Li, B. Liu, C. Redshaw, B. Wu, X.-J. Yang*, Cyclotrimerization of alkynes catalyzed by a self-supported cyclic tri-nuclear nickel(0) complex with α-diimine ligands. Dalton Trans., 2019, 48, 4643–4649.

15. J. Wang, J. Wang, L. Shen, Y. Zhao*, B. Wu, X.-J. Yang*. Reactions of Dianionic α-Diimine Supported Dimagnesium(I) Compound [K(THF)3]2[LMg?MgL] with Nitriles. Organometallics, 2019, 38, 2674?2682.

16. W. Chen, Y. Zhao,* W. Xu, J.-H. Su, L. Shen, L. Liu, B. Wu, X.-J. Yang*, Reductive linear- and cyclo-trimerization of isocyanides by an Al?Al-bonded compound. Chem. Commun. 2019, 55, 9452–9455.